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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

 

chat-dong-ran

 

This material is severely corrosive to the eyes and may cause delayed keratitis. The normally prescribed 15 minute eye irrigation after exposure may be difficult because of the severe pain. The prior installation of a topical ocular anesthetic is essential to facilitate a comprehensive ocular lavage. If swallowed, do not induce vomiting. Give patient plenty of water to drink. Ingestion of this corrosive material may result in severe ulceration, inflammation, and possible perforation of the upper alimentary tract, with hemorrhage and fluid loss. Aspiration of this material during induced emesis can result in severe lung injury. Contact a Poison Control Center for additional treatment information. Treat any additional effects

symptomatically.

 

 

Product label name

 

#PLND33241

 

Supplier

 

Akzo Nobel Polymer Chemicals bv

 

Stationsplein

 

4 PO Box 247

 

NL-3800 AE Amersfoort

 

Tel.: +31-334676767

 

Emergency telephone

 

+ 31 570679211 (Fax. + 31 570679801)

 

Akzo Nobel Chemicals-Deventer-NL

 

Intended use

 

polymerization initiator

 

Date of first issue

 

2004/08/20

 

Date of last issue / Revision #

 

2004/08/31 / 0.01

 

 

2. COMPOSITION/INFORMATION ON INGREDIENTS

 

This product is to be considered as a preparation in conformance to EC directives

 

Information on hazardous ingredients

 

Chemical description

 

Methyl ethyl ketone peroxide, in solvent mixture

 

Composition / information on ingredients

 

Number

 

% w/w

 

CAS-number

 

Chemical name

 

1

 

35.00 - 45.00

 

1338-23-4

 

Methyl ethyl ketone peroxide

 

2

 

1.00 - 5.00

 

7722-84-1

 

Hydrogen peroxide

 

3

 

10.00 - 20.00

 

111-46-6

 

Diethylene glycol

 

4

 

20.00 - 45.00

 

131-11-3

 

Dimethyl phthalate

 

5

 

3.00 - 7.00

 

78-93-3

 

Methyl ethyl ketone

 

 

 

 

Annex-1 number

 

EC-number

 

Symbol(s)

 

Risk-phrase(s)

 

1

 

 

215-661-2

 

C E

 

R02 R22 R34 R07

 

2

 

008-003-00-9

 

231-765-0

 

C O

 

R34 R08

 

3

 

603-140-00-6

 

203-872-2

 

Xn

 

R22

 

4

 

 

205-011-6

 

 

None

 

5

 

606-002-00-3

 

201-159-0

 

F Xi

 

R11 R36 R66 R67

 

Other information

 

Balance: non-hazardous ingredients.

 

 

3. HAZARDS IDENTIFICATION

 

May cause fire.

 

Harmful if swallowed.

 

Causes burns.

 

4. FIRST AID MEASURES

 

Symptoms and effects


Harmful if swallowed. Causes burns. Causes injury to the cornea and eyelids. Risk of serious damage to eyes.

 

First aid

 

General

 

Call a physician immediately.

 

Inhalation


Remove to fresh air. If not breathing, give artificial respiration. Oxygen may additionally be given, by trained personnel, if it is available. Get medical attention immediately.

 

Skin


Immediately start continuous flushing of skin with water for at least 15 minutes, while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean or destroy contaminated shoes.

 

Eye


Immediately start continuous flushing of eyes with water for at least 15 minutes. If easy to do, contact lenses should be removed during the flushing, by trained personnel. Hold the eyelids apart during the flushing to ensure rinsing the entire surface of the eye and lids with water. Get medical attention immediately.

 

Ingestion


DO NOT induce vomiting. Get medical attention immediately by calling a physician or a poison control center. If victim is conscious and alert, give a cupful of water. Never give anything by mouth to an unconscious or convulsing person. If vomiting occurs, the patient should lie on their left side while vomiting to reduce the risk of aspiration.

 

Advice to physician


This material is severely corrosive to the eyes and may cause delayed keratitis. The normally prescribed 15 minute eye irrigation after exposure may be difficult because of the severe pain. The prior installation of a topical ocular anesthetic is essential to facilitate a comprehensive ocular lavage. If swallowed, do not induce vomiting. Give patient plenty of water to drink. Ingestion of this corrosive material may result in severe ulceration, inflammation, and possible perforation of the upper alimentary tract, with hemorrhage and fluid loss. Aspiration of this material during induced emesis can result in severe lung injury. Contact a Poison Control Center for additional treatment information. Treat any additional effects symptomatically.

 

 

5. FIRE-FIGHTING MEASURES

 

Extinguishing media


waterspray, alcohol resistant foam, sand, dry chemical powder, CO2.

 

Unsuitable extinguishing media


halones.

 

Special exposure hazards


CAUTION: reignition may occur. Decomposition under effect of heating (See also Section Hazardous decomposition products). If involved in a fire, it will support combustion. Vapours may form explosive mixtures with air. In case of fire and/or explosion do not breathe fumes.

 

Hazardous decomposition/


combustion products Carbon dioxide, Water, Acetic acid, Formic acid, Propanoic acid, Methyl ethyl ketone

 

Protective equipment


Firefighters must wear fire resistant protective equipment. Wear approved respirator and protective gloves

 

Other information


Evacuate all non-essential personnel. Extinguish a small fire with powder or carbon dioxide then apply water to prevent re-ignition. Cool closed containers with water. Water used to extinguish a fire should not be allowed to enter the drainage system or water courses. After a fire, ventilate thoroughly the area and soak with water, clean the walls and metallic surfaces.

 

 

6. ACCIDENTAL RELEASE MEASURES

 

Personal precautions


Do not breathe fumes/vapour. Avoid contact with skin and eyes. For personal protection see Section 8.

 

Environmental precautions


Do not allow to enter drains or water courses.

 

Methods for cleaning up


Stop leakage if possible. Eliminate all sources of ignition, and do not generate flames or sparks. Collect as much as possible in a clean container for (preferable) reuse or disposal. Cover the remainder with inert absorbent (e.g. vermiculite) for disposal. Keep contents moist. The waste should NOT be confined. Flush surroundings with large amounts of water.

 

Other information


CAUTION: reignition may occur. Vapours are heavier than air and may spread along floors. Vapours may travel to a source of ignition and flash back. Evacuate personnel to safe area.

 

7. HANDLING AND STORAGE

 

Handling


Never weigh out in the storage room. When using do not eat, drink or smoke. Do not pipet by mouth. Do not breathe fumes/vapour. Handle in well ventilated areas. Eliminate all sources of ignition, and do not generate flames or sparks.Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal compounds (e.g. accelerators, driers, metal soaps). Keep product and emptied container away from heat and sources of ignition. Confinement must be avoided. Avoid contact with skin and eyes. Avoid Incompatible materials (See Section 10).

 

Fire and explosion prevention


Use explosion protected equipment. Keep away from sources of ignition - No moking. Vapours are heavier than air and may spread along floors. Use non-sparking tools in area's where explosive vapor air mixtures may occur. Do not cut or weld on or near this container even when empty.

 

Storage requirements


Store in accordance with local/national regulations. Keep away from food, drink and animal feedingstuffs. Store in a dry well ventilated place away from sources of heat and direct sunlight. Store separate from other chemicals. Keep only in the original container. Keep container upright to prevent leakage.

 

Storage


Avoid temperatures below -10 °C. If product freezes or separates, contact Akzo Nobel.

 

For maximum quality store below: 40 °C.

 

Other information


It is recommended to use electrical equipment of temperature group T3. However, autoignition can never be excluded. Wash hands thoroughly after handling or contact. Keep working clothing separately and do not take them home.

 

NR-7-UK-HSE Guidance (07)


A COSHH assessment necessary to ensure compliance.

 

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

 

Engineering controls


Ensure good ventilation and local exhaustion of the working area.

 

Explosion proof ventilation recommended.

 

Personal protection

 

Respiratory


In case of insufficient ventilation wear suitable respiratory equipment (respirator with Filter A).

 

Hand


Wear suitable protective gloves of neoprene or synthetic rubber

 

Eye


Wear eye/face protection.

 

Skin and body


Wear suitable protective clothing

 

Other information


Emergency-shower and facilities for rinsing eyes must be accessible. Launder clothes before reuse.

 

Methyl ethyl ketone peroxide

 

Agency OES-STEL

 

1.500 mg/m³

 

Hydrogen peroxide

 

ency OES-STEL

 

2.800 mg/m³

 

Agency OES-TWA

 

1.400 mg/m³

 

Diethylene glycol

 

Agency OES-TWA

 

101.000 mg/m³

 

Dimethyl phthalate

 

Agency OES-STEL

 

5.000 ppm

 

Methyl ethyl ketone

 

Agency OES-STEL

 

300.000 mg/m³

 

OES-STEL = , OES-TWA = MEL-STEL=

 

 

9. PHYSICAL AND CHEMICAL PROPERTIES

 

Appearance

 

clear liquid

 

Colour

 

colourless

 

Odour

 

faint

 

Boiling point/range

 

not applicable (Decomposes)

 

Melting point/range

 

Solidifies at or below -10°C / 14°F

 

Flash point

 

37°C / 99°F (closed cup)

>63°C / >145°F (open cup)

 

Flammability

 

Decomposition products may be flammable.

 

Autoignition temperature

 

Test method not applicable (See Section 7)

 

Explosive properties

 

No

 

Explosion limits

 

not determined

 

Oxidizing properties

 

not applicable

 

Vapour pressure

 

not determined

 

Density

 

1120 kg/m³ (20°C / 68°F)

Specific gravity = 1.12 (20°C / 68°F)

 

Bulk density

 

not applicable

 

Solubility in water

 

Partly miscible with water at 20°C / 68°F

 

Solubility in other solvents

 

Miscible with phthalates at 20°C / 68°F

 

pH value

 

slightly acidic

 

Partition coefficient n-octanol/water

 

not determined

 

Relative vapour density (air=1)

 

not determined

 

Viscosity

 

9.8 - 10.0 %

 

Peroxide content

 

36-50 %

 

Autoignition temperature

 

Test method not applicable (See Section 7)

 

SADT

 

55 °C. See also Section 10.

 

Explosion limits

 

not determined

 

 

10. STABILITY AND REACTIVITY

 

 

 

Stability


SADT - (Self accelerating decomposition temperature) is the lowest temperature at which self accelerating decomposition may occur with a substance in the packaging as used in transport. A dangerous self-accelerating decomposition reaction and, under certain circumstances, explosion or fire can be caused by thermal decomposition at and above the following temperature: 55 °C. Contact with incompatible substances can cause decomposition at or below the SADT 55 °C.

 

Conditions to avoid


Avoid temperatures below -10 °C. To maintain quality store in original closed container below: 40 °C. Confinement must be avoided.

 

Incompatible materials


Avoid contact with rust, iron and Copper. Contact with incompatible materials such as acids, alkalies, heavy metals and reducing agents will result in hazardous decomposition. Do not mix with peroxide accelerators. Use only Stainless steel 316, PVC, polyethylene or glass-lined equipment.

 

polymerization


Polymerization does not occur.

 

Decomposition


Acetic acid, Formic acid, Propanoic acid, Methyl ethyl ketone

 

Other information

 

Emergency procedures will vary depending on conditions. The customer must have an emergency response plan in place. Contact Akzo Nobel for assistance with developing an emergency response plan.

 

 

11. TOXICOLOGICAL INFORMATION

 

 

No experimental toxicological data on the preparation as such available. The following data are

 

applicable to the ingredient(s) listed below.

 

Methyl ethyl ketone peroxide

 

Acute toxicity

 

rat:1017 mg/kg

 

Dermal LD50

 

rat:4000 mg/kg

 

Inhalation LC50

 

rat:17 mg/l ; 4 hours exposure time

 

Irritation

 

Skin

 

Corrosive

 

Eye

 

Corrosive

 

Sensitization

 

Not sensitizing

 

Genotoxicity

 

Ames test: Not mutagenic

 

Name

 

Methyl ethyl ketone peroxide, 40 % in Dimethyl

 

Phthalate

 

Diethylene glycol

 

Acute toxicity

 

Oral LD50

 

Harmful if swallowed.

 

Dermal LD50

 

rabbit: >10.000 mg/kg

 

Inhalation LC50

 

9300 mg/m³ (6.5 hours )

 

Irritation

 

Skin

 

Mildly irritating

 

Eye

 

Minimally irritating

 

Name

 

Dimethyl phthalate

 

Methyl ethyl ketone

 

Acute toxicity

 

Oral LD50

 

at: 2737 mg/kg

 

Dermal LD50

 

rabbit 6480 mg/kg

 

Inhalation LC50

 

rat 23.5000 mg/m³

 

Irritation

 

Skin

 

Moderately irritating

 

Eye

 

Moderately irritating

 

Name

 

Methyl ethyl ketone

 

12. ECOLOGICAL INFORMATION

 

 

No experimental ecological data are available on the preparation as such. The following data are applicable to the ingredient(s) listed below

 

Methyl ethyl ketone peroxide

 

Ecotoxicity

 

Name

 

Methyl ethyl ketone peroxide, 40 % in Dimethyl

Phthalate

 

Fish

 

Acute toxicity, 96h-LC50 = 44.2 mg/l. ( Poecilia reticulata.)

 

Bacteria

 

Activated sludge respiration inhibition test EC50 = 48.0mg/l.

 

Fate

 

Degradation Biotic

 

Readily biodegradable ( Closed bottle test ).

 

Dimethyl phthalate

 

Ecotoxicity

 

Dimethyl phthalate

 

Fish

 

Lepomis macrochirus: 96h-LC50: 420 ppm

 

Algae

 

Selenastrum capricornutum: 39.8 mg/l ( 96h-IC50 )

 

Fate

 

Degradation Biotic

 

Readily biodegradable.

 

Other information

 

Bio Concentration Factor (BCF) fish 5.4 (24 hours )

 

Methyl ethyl ketone

 

Ecotoxicity

 

Methyl ethyl ketone

 

Fish

 

Lepomis macrochirus: 96h-LC50: 3.22 g/l

 

Fate

 

Degradation Biotic

 

Readily biodegradable.

 

Other information

 

Naturally occuring substance

 

13. DISPOSAL CONSIDERATIONS

 

 

Product


#IDISP0088. Waste disposal in accordance with regulations (most probably ontrolled incineration).

 

Contaminated packaging


According to local regulations. Emptied container might retain product residues. Follow all warnings even after the container is emptied.

 

Other information


For further advice contact manufacturer.

 

Abfallschlüsselnummer


Waste should be regarded as special waste for disposal. Please refer to your specific industry in the European Waste Catalogue.

 

14. TRANSPORT INFORMATION

 

Land transport (ADR/ RID)

 

ADR class

 

5.2

 

ADR Classification Code

 

P1

 

RID class

 

5.2

 

Substance Identification No.

 

3105

 

TREM-Card

 

CEFIC TEC(R)- 52GP1-L

 

UN number

 

3105

 

Proper Shipping Name

 

Organic peroxide type d, liquid ( Methyl ethyl ketone peroxide )

Other information

 

Label(s); 5.2

 

Sea transport (IMDG-code/ IMO)

 

Class

 

5.2

 

Packing group

 

II

 

UN number

 

3105

 

EMS

 

F-J, S-R

 

 

Marine pollutant

 

No

 

Proper Shipping Name

 

Organic peroxide type d, liquid ( Methyl ethyl ketone peroxide )

 

Other information

 

Label(s); 5.2

 

Air transport (ICAO-TI/ IATA-DGR)

 

UN number

3105

 

Class

5.2

 

Proper Shipping Name

 

Organic peroxide type d, liquid ( Methyl ethyl ketone peroxide )

 

Other information

 

Label(s); 5.2

 

Other information


The control temperature is the maximum temperature at which the formulation can be transported safely during a prolonged period of time.

 

15. REGULATORY INFORMATION

 

Chemical description


#PLND33241

 

Labelling according to EC directives

 

EC-number


not applicable

 

R(isk) phrase(s)

 

Code

 

Description

 

R07.

 

May cause fire

 

R22.

 

Harmful if swallowed.

 

R34.

 

Causes burns.

 

S(afety) phrase(s)

 

Code

 

Description

 

S03/07.

 

Keep container tightly closed in a cool place.

 

S14B.

 

Keep away from reducing agents (e.g. amines), acids, alkalies and heavy metal compounds (e.g. accelerators, driers, metal soaps).

 

S36/37/39.

 

Wear suitable protective clothing, gloves and eye/face rotection.

 

S45.

 

In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

 

S50D.

 

Do not mix with peroxide-accelerators or reducing agents.

 

 

Symbol(S)

 

 

 

CORROSIVE (C)

 

OXIDIZING (O)

 

Other information

 

Substance and/or product listed in Directive 96/82/EC.

 

16. OTHER INFORMATION

 

This information only concerns the above mentioned product and does not need to be valid if used with other product(s) or in any process. The information is to our best present knowledge correct and complete and is given in good faith but without warranty. It remains the user's own responsibility to make sure that the information is appropriate and complete for his special use of this product.

 

R-phrase information

 

Chemical name

 

Risk-phrase(s)

 

 

Methyl ethyl ketone peroxide

 

R02 R22 R34 R07

 

Risk of explosion by shock, friction, fire or other sources of ignition Harmful if swallowed Causes burns May cause

fire

 

Hydrogen peroxide

 

R34 R08

 

Causes burns Contact with combustible material may cause fire

 

Diethylene glycol

 

R22

 

Harmful if swallowed

 

Dimethyl phthalate

 

None

 

None

 

Methyl ethyl ketone

 

R11 R36 R66 R67

 

Highly flammable Irritating to eyes

Repeated exposure may cause skin dryness or cracking Vapours may cause drowsiness and dizziness

 

History

 

Date of printing/pdf file generated

 

2004/08/31

 

Revision

 

0.01

 

Composed by

 

J.W. Wessels.

 

Changes were made in section

 

9

 

 


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